Osmotic pressure is directly proportional to the number of solute particles in solution. Since KCl dissociates into two ions (K\(^+\) and Cl\(^-\)) in solution, a 1 M KCl solution will have a higher osmotic pressure than a 1 M urea solution, which does not dissociate into ions. Therefore, the 1 M KCl solution will have a higher osmotic pressure.