\( O_2 \) gas has a higher \( K_H \) value because a higher \( K_H \) means lower solubility of the gas in liquid.
Step 1: Understanding Henry’s Law Constant (\( K_H \)) Henry’s law states that: \[ C = K_H P \] where \( C \) is the concentration of the gas in liquid, \( K_H \) is Henry’s law constant, and \( P \) is the partial pressure of the gas.
Step 2: Relationship Between \( K_H \) and Solubility \[ K_H \propto \frac{1}{\text{Solubility of Gas}} \] Since \( CO_2 \) is more soluble in water than \( O_2 \), it has a lower \( K_H \) value. Thus, \( O_2 \) has a higher \( K_H \).
According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this concept is valid in ecological systems (isotopic mixtures of an element, hydrocarbons mixtures, etc.). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This law is further supported by the fact that Raoult’s law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.
Answer the following questions:
(a) Give one example of miscible liquid pair which shows negative deviation from Raoult’s law. What is the reason for such deviation?
(b) (i) State Raoult’s law for a solution containing volatile components.
OR
(ii) Raoult’s law is a special case of Henry’s law. Comment.
(c) Write two characteristics of an ideal solution.
“One of these days you’re going to talk yourself into a load of trouble,” her father said aggressively. What do you learn about Sophie’s father from these lines? (Going Places)