Question:

Given below are two statements, one is labelled as Assertion $A$ and the other is labeled as Reason $R$ 
Assertion A : The alkali metals and their salts impart characteristic colour to reducing flame 
Reason R : Alkali metals can be detected using flame tests 
In the light of the above statements, choose the most appropriate answer from the options given below

Updated On: Mar 19, 2025
  • $A$ is not correct but $R$ is correct
  • Both $A$ and $R$ are correct but $R$ is NOT the correct explanation of $A$
  • Both $A$ and $R$ are correct and $R$ is the correct explanation of $A$
  • $A$ is correct but $R$ is not correct
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The Correct Option is A

Solution and Explanation

Assertion A is incorrect. Alkali metals and their salts typically impart distinct colors to an oxidizing flame, not a reducing flame. When alkali metal salts are heated in a flame, they excite the metal ions, which then emit characteristic colors as they return to their ground state. These colors are observed in an oxidizing flame (such as that produced by a Bunsen burner with sufficient oxygen), not in a reducing flame, which lacks the necessary oxidizing conditions for such reactions to occur. 

Reason R is correct. Flame tests are indeed a common and reliable method for identifying alkali metals and other metal ions based on the characteristic colors they emit when heated. For example, lithium produces a red flame, sodium a bright yellow flame, and potassium a lilac flame. This principle is widely used in qualitative analysis.

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Concepts Used:

P-Block Elements

  • P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
  • P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.

P block elements consist of: