✅ Correct answer: 3s < 3p < 4s < 3d
Explanation:
According to the Moeller chart (also known as the Aufbau principle), electrons fill atomic orbitals in the order of increasing energy. The energy order of orbitals is determined using the n + l rule, where:
- n is the principal quantum number
- l is the azimuthal quantum number
If two orbitals have the same n + l value, the orbital with the lower n value has lower energy.
Using this rule:
- 3s (n + l = 3 + 0 = 3)
- 3p (n + l = 3 + 1 = 4)
- 4s (n + l = 4 + 0 = 4)
- 3d (n + l = 3 + 2 = 5)
So the correct order is:
3s < 3p < 4s < 3d
The correct answer is 3s < 3p < 4s < 3d. According to the Moeller chart, the energy levels of orbitals follow a specific order. For the orbitals in question, the energy order is: - 3s has the lowest energy, - 3p comes next, - 4s has lower energy than 3d, - 3d has the highest energy among these orbitals. Thus, the correct ascending order of their energies is 3s < 3p < 4s < 3d.
Regarding the molecular orbital (MO) energy levels for homonuclear diatomic molecules, the INCORRECT statement(s) is (are):
Which of the following statement is true with respect to H\(_2\)O, NH\(_3\) and CH\(_4\)?
(A) The central atoms of all the molecules are sp\(^3\) hybridized.
(B) The H–O–H, H–N–H and H–C–H angles in the above molecules are 104.5°, 107.5° and 109.5° respectively.
(C) The increasing order of dipole moment is CH\(_4\)<NH\(_3\)<H\(_2\)O.
(D) Both H\(_2\)O and NH\(_3\) are Lewis acids and CH\(_4\) is a Lewis base.
(E) A solution of NH\(_3\) in H\(_2\)O is basic. In this solution NH\(_3\) and H\(_2\)O act as Lowry-Bronsted acid and base respectively.