An ideal monatomic gas of $ n $ moles is taken through a cycle $ WXYZW $ consisting of consecutive adiabatic and isobaric quasi-static processes, as shown in the schematic $ V-T $ diagram. The volume of the gas at $ W, X $ and $ Y $ points are, $ 64 \, \text{cm}^3 $, $ 125 \, \text{cm}^3 $ and $ 250 \, \text{cm}^3 $, respectively. If the absolute temperature of the gas $ T_W $ at the point $ W $ is such that $ n R T_W = 1 \, J $ ($ R $ is the universal gas constant), then the amount of heat absorbed (in J) by the gas along the path $ XY $ is 
Match List - I with List - II.

1.24 g of $ {AX}_2 $ (molar mass 124 g mol$^{-1}$) is dissolved in 1 kg of water to form a solution with boiling point of 100.105$^\circ$C, while 2.54 g of $ {AY}_2 $ (molar mass 250 g mol$^{-1}$) in 2 kg of water constitutes a solution with a boiling point of 100.026$^\circ$C. $ K_{b(H_2O)} = 0.52 \, \text{K kg mol}^{-1} $. Which of the following is correct?
For the reaction:

The correct order of set of reagents for the above conversion is :
The center of a disk of radius $ r $ and mass $ m $ is attached to a spring of spring constant $ k $, inside a ring of radius $ R>r $ as shown in the figure. The other end of the spring is attached on the periphery of the ring. Both the ring and the disk are in the same vertical plane. The disk can only roll along the inside periphery of the ring, without slipping. The spring can only be stretched or compressed along the periphery of the ring, following Hooke’s law. In equilibrium, the disk is at the bottom of the ring. Assuming small displacement of the disc, the time period of oscillation of center of mass of the disk is written as $ T = \frac{2\pi}{\omega} $. The correct expression for $ \omega $ is ( $ g $ is the acceleration due to gravity): 
Let $ a_0, a_1, ..., a_{23} $ be real numbers such that $$ \left(1 + \frac{2}{5}x \right)^{23} = \sum_{i=0}^{23} a_i x^i $$ for every real number $ x $. Let $ a_r $ be the largest among the numbers $ a_j $ for $ 0 \leq j \leq 23 $. Then the value of $ r $ is ________.