To determine the final temperature of an ideal gas undergoing adiabatic expansion, we use the adiabatic process relation:
\( TV^{\gamma-1} = \text{constant} \)
For an initial state with temperature \( T_1 = T \) and volume \( V_1 = V \), and a final state with temperature \( T_2 \) and volume \( V_2 = 2V \), the equation becomes:
\( TV^{\gamma-1} = T_2(2V)^{\gamma-1} \)
Simplifying gives:
\( T V^{\gamma-1} = T_2 \cdot 2^{\gamma-1} \cdot V^{\gamma-1} \)
Cancel out \( V^{\gamma-1} \) on both sides:
\( T = T_2 \cdot 2^{\gamma-1} \)
Solve for \( T_2 \):
\( T_2 = \frac{T}{2^{\gamma-1}} \)
Given \( \gamma = \frac{5}{3} \), calculate \( \gamma-1 \):
\( \gamma-1 = \frac{5}{3} - 1 = \frac{2}{3} \)
Substitute back to find \( T_2 \):
\( T_2 = \frac{T}{2^{2/3}} \)
The final temperature \( T_2 \) is \( \frac{T}{2^{2/3}} \).
A sample of n-octane (1.14 g) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is 5 kJ K\(^{-1}\). As a result of combustion, the temperature of the calorimeter increased by 5 K. The magnitude of the heat of combustion at constant volume is ___
A perfect gas (0.1 mol) having \( \bar{C}_V = 1.50 \) R (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is ____ J (nearest integer) [Given : R = 0.082 L atm K\(^{-1}\)] 