Question:

An ideal gas is kept in a closed container. If the temperature is doubled and the volume of the container is reduced to half, the gas pressure is:

Updated On: Apr 7, 2025
  • Unchanged 

  • Halved

  • Doubled

  • Increased by 4 times

  • Increased by 16 times

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The Correct Option is D

Approach Solution - 1

Given:

  • Ideal gas in a closed container (fixed amount of gas, n = constant)
  • Initial conditions: Temperature \( T_1 \), Volume \( V_1 \), Pressure \( P_1 \)
  • Final conditions:
    • Temperature \( T_2 = 2T_1 \) (doubled)
    • Volume \( V_2 = \frac{V_1}{2} \) (halved)

Step 1: Apply Ideal Gas Law

The ideal gas law states:

\[ PV = nRT \]

For the initial and final states:

\[ P_1 V_1 = nRT_1 \]

\[ P_2 V_2 = nRT_2 \]

Step 2: Relate Pressures

Divide the final state equation by the initial state equation:

\[ \frac{P_2 V_2}{P_1 V_1} = \frac{T_2}{T_1} \]

Substitute \( V_2 = \frac{V_1}{2} \) and \( T_2 = 2T_1 \):

\[ \frac{P_2 \left(\frac{V_1}{2}\right)}{P_1 V_1} = \frac{2T_1}{T_1} \]

Simplify:

\[ \frac{P_2}{2P_1} = 2 \]

\[ P_2 = 4P_1 \]

Conclusion:

The gas pressure is increased by 4 times.

Answer: \(\boxed{D}\)

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Approach Solution -2

1. State the ideal gas law:

The ideal gas law relates pressure (P), volume (V), and temperature (T) of an ideal gas:

\[PV = nRT\]

where:

  • n is the number of moles of gas (constant in this case)
  • R is the ideal gas constant (constant)

2. Set up the initial and final conditions:

Initial conditions:

\[P_1V_1 = nRT_1\]

Final conditions (temperature is doubled, volume is halved):

\[P_2V_2 = nRT_2\]

\[P_2(\frac{1}{2}V_1) = nR(2T_1)\]

3. Solve for the final pressure:

Divide the final condition equation by the initial condition equation:

\[\frac{P_2(\frac{1}{2}V_1)}{P_1V_1} = \frac{nR(2T_1)}{nRT_1}\]

Simplify:

\[\frac{\frac{1}{2}P_2}{P_1} = \frac{2}{1}\]

\[\frac{P_2}{2P_1} = 2\]

\[P_2 = 4P_1\]

Therefore, the final pressure \(P_2\) is four times the initial pressure \(P_1\).

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Concepts Used:

Kinetic Molecular Theory of Gases

Postulates of Kinetic Theory of Gases:

  • Gases consist of particles in constant, random motion. They continue in a straight line until they collide with each other or the walls of their container. 
  • Particles are point masses with no volume. The particles are so small compared to the space between them, that we do not consider their size in ideal gases.
  • Gas pressure is due to the molecules colliding with the walls of the container. All of these collisions are perfectly elastic, meaning that there is no change in energy of either the particles or the wall upon collision.  No energy is lost or gained from collisions. The time it takes to collide is negligible compared with the time between collisions.
  • The kinetic energy of a gas is a measure of its Kelvin temperature. Individual gas molecules have different speeds, but the temperature and
    kinetic energy of the gas refer to the average of these speeds.
  • The average kinetic energy of a gas particle is directly proportional to the temperature. An increase in temperature increases the speed in which the gas molecules move.
  • All gases at a given temperature have the same average kinetic energy.
  • Lighter gas molecules move faster than heavier molecules.