Question:

An electron in Bohr model of hydrogen atom makes a transition from energy level \(-1.51 \, \text{eV}\) to \(-3.40 \, \text{eV}\). Calculate the change in the radius of its orbit. The radius of orbit of electron in its ground state is \(0.53 \, \text{\AA}\).

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In the Bohr model, the radius of the electron's orbit is proportional to the square of the principal quantum number \( n \).
Updated On: Feb 26, 2025
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Solution and Explanation

The radius \( r_n \) of the electron's orbit in the Bohr model is given by: \[ r_n = r_1 n^2 \] where \( r_1 = 0.53 \, \text{\AA} \) is the radius of the ground state orbit, and \( n \) is the principal quantum number. The energy levels are given by: \[ E_n = -\frac{13.6 \, \text{eV}}{n^2} \] For \( E_n = -1.51 \, \text{eV} \): \[ -1.51 = -\frac{13.6}{n_1^2} \implies n_1^2 = \frac{13.6}{1.51} \implies n_1 = 3 \] For \( E_n = -3.40 \, \text{eV} \): \[ -3.40 = -\frac{13.6}{n_2^2} \implies n_2^2 = \frac{13.6}{3.40} \implies n_2 = 2 \] The radii of the orbits are: \[ r_{n_1} = r_1 n_1^2 = 0.53 \times 9 = 4.77 \, \text{\AA} \] \[ r_{n_2} = r_1 n_2^2 = 0.53 \times 4 = 2.12 \, \text{\AA} \] The change in radius is: \[ \Delta r = r_{n_1} - r_{n_2} = 4.77 - 2.12 = 2.65 \, \text{\AA} \] Thus, the change in the radius of the orbit is \( 2.65 \, \text{\AA} \).
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