Gauss's law states that the electric flux \( \Phi_E \) through a closed surface is given by:
\[
\Phi_E = \frac{q_{{enclosed}}}{\epsilon_0}
\]
When the charge \( q \) is placed at the center of the cube, the total flux is \( \frac{q}{\epsilon_0} \). Since the cube has 6 faces, the flux through each face will be equally distributed. Therefore, the flux through one face is:
\[
\frac{q}{6 \epsilon_0}
\]
Hence, the correct answer is (b).