1. Electric Potential due to a Point Charge:
The electric potential \( V \) at a point due to a point charge \( Q \) is given by the formula:
\[ V = \frac{kQ}{r} \]
Where:
2. Work Done in Moving a Charge:
The work \( W \) done in moving a charge \( q \) from one point to another in an electric field is given by:
\[ W = q \Delta V \]
Where:
3. Electric Potential at Points A and C:
The charge \( -6 \, \mu C \) is at the center B of the semicircle. The potential at any point on the semicircle due to this central charge will be the same, as the distance from the center (radius) is constant for both points A and C.
Thus, the electric potential at points A and C is the same because both points are equidistant from the central charge \( -6 \, \mu C \).
4. Work Done:
Since the electric potential at both points A and C is the same, the potential difference \( \Delta V \) is zero. Therefore, the work done in moving the charge \( +5 \, \mu C \) from point C to point A is:
\[ W = q \Delta V = 5 \, \mu C \times 0 = 0 \]
5. Conclusion:
(a) Calculate the standard Gibbs energy (\(\Delta G^\circ\)) of the following reaction at 25°C:
\(\text{Au(s) + Ca\(^{2+}\)(1M) $\rightarrow$ Au\(^{3+}\)(1M) + Ca(s)} \)
\(\text{E\(^\circ_{\text{Au}^{3+}/\text{Au}} = +1.5 V, E\)\(^\circ_{\text{Ca}^{2+}/\text{Ca}} = -2.87 V\)}\)
\(\text{1 F} = 96500 C mol^{-1}\)
Define the following:
(i) Cell potential
(ii) Fuel Cell
Calculate the emf of the following cell at 25°C:
\[ \text{Zn(s)} | \text{Zn}^{2+}(0.1M) || \text{Cd}^{2+}(0.01M) | \text{Cd(s)} \] Given: \[ E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.40 \, V, \, E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, V \] \[ [\log 10 = 1] \]