Let the principal amount be \(P\). Then the amount after 25 years is \(5P\).
Simple Interest (SI) \(= \text{Amount} - \text{Principal} = 5P - P = 4P\).
Using the formula for simple interest:
\[
SI = \frac{P \times R \times T}{100}
\]
where \(R\) is the rate of interest and \(T = 25\) years. Substituting:
\[
4P = \frac{P \times R \times 25}{100}
\]
Dividing both sides by \(P\):
\[
4 = \frac{25R}{100} \implies 4 \times 100 = 25R \implies 400 = 25R \implies R = \frac{400}{25} = 16
\]
So, the rate of simple interest is 16% per annum.