Let the principal amount be \(P\), rate of interest per annum be \(R\%\), and time \(T = 25\) years.
The amount after 25 years is 5 times the principal, so:
\[
A = 5P
\]
Simple Interest (SI) = Amount - Principal =
\[
SI = 5P - P = 4P
\]
Formula for Simple Interest:
\[
SI = \frac{P \times R \times T}{100}
\]
Substitute values:
\[
4P = \frac{P \times R \times 25}{100}
\]
\[
4 = \frac{25R}{100} = \frac{R}{4}
\]
Multiply both sides by 4:
\[
16 = R
\]
This calculation gives \(R = 16\%\). But check carefully:
Actually,
\[
4P = \frac{P \times R \times 25}{100} \implies 4 = \frac{25R}{100} \implies 4 = \frac{R}{4} \implies R = 16\%
\]
So the rate is \(16\%\) (correct answer is (a)).