We know that the average translational kinetic energy of molecules in an ideal gas is related to the pressure, volume, and temperature by the ideal gas law:
\[
\frac{3}{2} n k_B T = \frac{1}{2} m v^2
\]
For a monatomic gas, the average kinetic energy of a molecule is given by:
\[
\text{K.E.} = \frac{3}{2} k_B T
\]
We can also use the equation for the pressure-volume relationship for gases:
\[
PV = nRT
\]
Given the total energy \( E \) is \( 4.5 \times 10^5 \, \text{J} \) and the volume \( V = 10 \, \text{liters} = 10 \times 10^{-3} \, \text{m}^3 \), we can now calculate the pressure by substituting these values into the equation. The pressure \( P \) comes out to be \( 30 \times 10^6 \, \text{Nm}^{-2} \).
Thus, the pressure in the vessel is \( \boxed{30 \times 10^6 \, \text{Nm}^{-2}} \).