Comprehension

A trinitro compound, 1,3,5-tris-(4-nitrophenyl)benzene, on complete reaction with an excess of Sn/HCl gives a major product, which on treatment with an excess of NaNO2/HCl at 0°C provides P as the product. P, upon treatment with excess of H2O at room temperature, gives the product Q. Bromination of Q in aqueous medium furnishes the product R. The compound P upon treatment with an excess of phenol under basic conditions gives the product S. The molar mass difference between compounds Q and R is 474 g mol–1 and between compounds P and S is 172.5 g mol–1.

Question: 1

The number of heteroatoms present in one molecule of R is ______ . 
[Use: Molar mass (in g mol–1): H = 1, C = 12, N = 14, O = 16, Br = 80, Cl = 35.5 Atoms other than C and H are considered as heteroatoms]

Updated On: Mar 30, 2024
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Correct Answer: 9

Solution and Explanation

A trinitro compound
Number of Heteroatoms in R is 9.
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Question: 2

The total number of carbon atoms and heteroatoms present in one molecule of S is ______ . 
[Use: Molar mass (in g mol–1): H = 1, C = 12, N = 14, O = 16, Br = 80, Cl = 35.5 Atoms other than C and H are considered as heteroatoms] 

Updated On: Mar 30, 2024
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Correct Answer: 51

Solution and Explanation

A trinitro compound
Number of Carbon atoms + Number of Heteroatoms = 51
So, the answer is 51.
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