Let the sum of money be \( P \) and the amount after \( R \) years be \( 2P \) (since the sum doubles).
The formula for simple interest is:
\[
\text{Simple Interest} = \frac{P \times R \times T}{100},
\]
where \( P \) is the principal, \( R \) is the rate of interest, and \( T \) is the time in years.
Since the amount doubles, the simple interest is equal to the principal amount:
\[
\text{Simple Interest} = P.
\]
Substitute in the formula:
\[
P = \frac{P \times R \times R}{100} \quad \Rightarrow \quad 100 = R^2 \quad \Rightarrow \quad R = 10.
\]
Thus, the annual rate of interest is 10%, corresponding to option (2).