When a larger spherical shell and a smaller solid sphere are connected, the potential must equalize. Since potential \( V \) for a sphere is given by \( V = \frac{Q}{4\pi \epsilon_0 R} \), and \( R_A>R_B \), the charges rearrange to maintain \( V_A = V_B \), resulting in:
\[
\frac{Q_A}{R_A} = \frac{Q_B}{R_B} \implies Q_A R_B = Q_B R_A
\]
Since \( R_A>R_B \), it follows that \( Q_A>Q_B \) to balance the equation.