Question:

A sample of $0.42 \,mg \,{ }^{233} UF _{6}$ shows an activity of $9.88 \times 10^{4}$ count per second. Its $t_{1 / 2}$ is

Updated On: Jul 2, 2022
  • $5.13 \times 10^{12} yr$
  • $1.628 \times 10^{5} yr$
  • $2.94 \times 10^{-9} yr$
  • $2.35 \times 10^{8} yr$
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The Correct Option is B

Solution and Explanation

Molecular mass of $U F_{6}=233+19 \times 6=347$ $\frac{d N}{d t} =k N $ $9.88 \times 10^{4} =k \times \frac{0.42 \times 10^{-3} \times 6.023 \times 10^{23}}{347}$ $\therefore k =1.35 \times 10^{-13}$ $k =\frac{0.693}{t_{1 / 2}}$ [$\because$ Radioactive changes follow Ist order kinetics.] or $ t_{1 / 2} =\frac{0.693}{1.35 \times 10^{-13}} s $ $=5.13 \times 10^{12} s $ $=1.628 \times 10^{5} \,yr .$
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Questions Asked in AIIMS exam

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Concepts Used:

Rate of a Chemical Reaction

The rate of a chemical reaction is defined as the change in concentration of any one of the reactants or products per unit time.

Consider the reaction A → B,

Rate of the reaction is given by,

Rate = −d[A]/ dt=+d[B]/ dt

Where, [A] → concentration of reactant A

[B] → concentration of product B

(-) A negative sign indicates a decrease in the concentration of A with time.

(+) A positive sign indicates an increase in the concentration of B with time.

Factors Determining the Rate of a Reaction:

There are certain factors that determine the rate of a reaction:

  1. Temperature
  2. Catalyst
  3. Reactant Concentration
  4. Chemical nature of Reactant
  5. Reactant Subdivision rate