Step 1: Understanding the angle of deviation.
The angle of deviation \( D \) for a prism is given by the relation:
\[
D = i + e - A
\]
where \( i \) is the angle of incidence, \( e \) is the angle of emergence, and \( A \) is the angle of the prism.
Step 2: Using the given values.
It is given that \( i = e = \frac{A}{3} \), so we can substitute into the formula for \( D \):
\[
D = \frac{A}{3} + \frac{A}{3} - A = \frac{2A}{3} - A = 30°
\]
Step 3: Conclusion.
Thus, the angle of deviation is 30°, which corresponds to option (D).