Question:

A radioactive nuclei has a half life of 693s. The activity of one mole of that nuclei sample is:(Avogadro's number=6.023 x1023 and In(2)=0.693) 

Updated On: Apr 7, 2025
  •  2×1010 Bq

  •  3.7×1010 Bq

  •  6.023×1020 Bq

  •  0.5×10-10 Bq

  •  1×1020 Bq

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The Correct Option is C

Approach Solution - 1

Given:

  • Half-life, \( T_{1/2} = 693 \, \text{s} \)
  • Avogadro's number, \( N_A = 6.023 \times 10^{23} \, \text{mol}^{-1} \)
  • \(\ln(2) = 0.693\)

Step 1: Calculate the Decay Constant (\( \lambda \))

The decay constant is given by:

\[ \lambda = \frac{\ln(2)}{T_{1/2}} = \frac{0.693}{693} = 0.001 \, \text{s}^{-1} \]

Step 2: Determine the Number of Nuclei (\( N \))

For 1 mole of nuclei:

\[ N = N_A = 6.023 \times 10^{23} \]

Step 3: Compute Activity (\( A \))

Activity is defined as:

\[ A = \lambda N = 0.001 \times 6.023 \times 10^{23} = 6.023 \times 10^{20} \, \text{Bq} \]

Conclusion:

The activity of one mole of the radioactive nuclei is \( 6.023 \times 10^{20} \, \text{Bq} \).

Answer: \(\boxed{C}\)

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Approach Solution -2

1. Define variables and given information:

  • t1/2 = 693 s (half-life)
  • NA = 6.023 × 10²³ (Avogadro's number)
  • ln(2) = 0.693
  • Activity (A) = ?

2. Calculate the decay constant (λ):

The decay constant is related to the half-life by the following equation:

\[t_{1/2} = \frac{\ln(2)}{\lambda}\]

\[\lambda = \frac{\ln(2)}{t_{1/2}} = \frac{0.693}{693 \, s} = 10^{-3} \, s^{-1}\]

3. Calculate the number of nuclei (N) in one mole:

One mole of any substance contains Avogadro's number of particles (in this case, nuclei):

\[N = N_A = 6.023 \times 10^{23}\]

4. Calculate the activity (A):

Activity is defined as the rate of decay and is given by:

\[A = \lambda N\]

\[A = (10^{-3} \, s^{-1})(6.023 \times 10^{23}) = 6.023 \times 10^{20} \, Bq\]

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Concepts Used:

Nuclei

In the year 1911, Rutherford discovered the atomic nucleus along with his associates. It is already known that every atom is manufactured of positive charge and mass in the form of a nucleus that is concentrated at the center of the atom. More than 99.9% of the mass of an atom is located in the nucleus. Additionally, the size of the atom is of the order of 10-10 m and that of the nucleus is of the order of 10-15 m.

Read More: Nuclei

Following are the terms related to nucleus:

  1. Atomic Number
  2. Mass Number
  3. Nuclear Size
  4. Nuclear Density
  5. Atomic Mass Unit