The de Broglie wavelength \(\lambda\) of a particle is given by the relation \(\lambda = \frac{h}{p}\), where \(h\) is the Planck constant and \(p\) is the momentum of the particle. The momentum \(p\) can be related to the kinetic energy \(K\) by the relation \(p = \sqrt{2mK}\), where \(m\) is the mass of the particle.
For the proton:
\[
p_{{proton}} = \sqrt{2m_{{proton}}K_{{proton}}}
\]
\[
\lambda_{{proton}} = \frac{h}{\sqrt{2m_{{proton}} \times 4.5 \, {MeV}}}
\]
For the alpha particle:
\[
p_{{alpha}} = \sqrt{2m_{{alpha}}K_{{alpha}}}
\]
\[
\lambda_{{alpha}} = \frac{h}{\sqrt{2m_{{alpha}} \times 0.5 \, {MeV}}}
\]
Since the mass of an alpha particle is approximately four times that of a proton, and considering the kinetic energies, the ratio of their wavelengths becomes:
\[
\frac{\lambda_{{proton}}}{\lambda_{{alpha}}} = \frac{\sqrt{2m_{{alpha}} \times 0.5 \, {MeV}}}{\sqrt{2m_{{proton}} \times 4.5 \, {MeV}}} = \frac{\sqrt{2 \times 4m_{{proton}} \times 0.5}}{\sqrt{2m_{{proton}} \times 4.5}} = \frac{2}{\sqrt{9}} = \frac{2}{3}
\]