A doublet is obtained when both dice show the same number, such as (1,1), (2,2), ..., (6,6).
There are 6 such outcomes out of a total of $6 \times 6 = 36$ outcomes when a pair of dice is thrown once.
So, the probability of getting a doublet in one trial is $\dfrac{6}{36} = \dfrac{1}{6}$.
Now, the dice are thrown twice.
Let $X$ be the number of doublets obtained in 2 independent trials.
Then $X$ follows a Binomial distribution with $n = 2$, $p = \dfrac{1}{6}$.
The expectation $E[X] = n.p = 2.\dfrac{1}{6} = \dfrac{2}{6} = \dfrac{1}{3}$.
So, the expected number of doublets is $\dfrac{1}{3}$.