For a particle to be removed with 100\% efficiency in a settling chamber, it must settle to the bottom of the chamber before it can exit horizontally. This condition is satisfied when the particle’s settling time through the height of the chamber is equal to the air's travel time through the length of the chamber, mathematically represented as:
\[ \frac{V_t}{H} = \frac{V_h}{L} \]
This balance ensures that particles have sufficient time to settle out of the airflow before exiting the chamber.