Given: - Ratio of specific heats, \( \gamma = \frac{4}{3} \) Step 1: Determine the fraction of heat used for work in an isobaric process For an isobaric process, the heat \( Q \) added to the gas is used to increase the internal energy \( \Delta U \) and to do work \( W \).
The relationship is given by: \[ Q = \Delta U + W \] For an ideal gas, the work done \( W \) in an isobaric process is: \[ W = P \Delta V = n R \Delta T \] The change in internal energy \( \Delta U \) is: \[ \Delta U = n C_v \Delta T \] The total heat added \( Q \) is: \[ Q = n C_p \Delta T \] The fraction of heat used for work is: \[ \frac{W}{Q} = \frac{n R \Delta T}{n C_p \Delta T} = \frac{R}{C_p} \] Given that \( \gamma = \frac{C_p}{C_v} \) and \( C_p = C_v + R \), we can express \( C_p \) as: \[ C_p = \frac{\gamma R}{\gamma - 1} \] Thus, \[ \frac{W}{Q} = \frac{R}{\frac{\gamma R}{\gamma - 1}} = \frac{\gamma - 1}{\gamma} \] Substituting \( \gamma = \frac{4}{3} \): \[ \frac{W}{Q} = \frac{\frac{4}{3} - 1}{\frac{4}{3}} = \frac{\frac{1}{3}}{\frac{4}{3}} = \frac{1}{4} = 0.25 \] Step 2: Convert the fraction to a percentage \[ 0.25 \times 100 = 25 % \] Final Answer: 25 %
A sample of n-octane (1.14 g) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is 5 kJ K\(^{-1}\). As a result of combustion, the temperature of the calorimeter increased by 5 K. The magnitude of the heat of combustion at constant volume is ___
A perfect gas (0.1 mol) having \( \bar{C}_V = 1.50 \) R (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is ____ J (nearest integer) [Given : R = 0.082 L atm K\(^{-1}\)] 
If the roots of $\sqrt{\frac{1 - y}{y}} + \sqrt{\frac{y}{1 - y}} = \frac{5}{2}$ are $\alpha$ and $\beta$ ($\beta > \alpha$) and the equation $(\alpha + \beta)x^4 - 25\alpha \beta x^2 + (\gamma + \beta - \alpha) = 0$ has real roots, then a possible value of $y$ is: