The internal energy of a monatomic gas is given by $U_\text{mono} = \frac{3}{2}nRT$, and the internal energy of a diatomic gas is given by $U_\text{di} = \frac{5}{2}nRT$, where:
We are given a mixture containing 2 moles each of monatomic and diatomic molecules. Thus, $n_\text{mono} = n_\text{di} = 2$. The total internal energy of the mixture is the sum of the internal energies of the individual gases:
$U_\text{total} = U_\text{mono} + U_\text{di}$
$U_\text{total} = \frac{3}{2}n_\text{mono}RT + \frac{5}{2}n_\text{di}RT$
$U_\text{total} = \frac{3}{2}(2)RT + \frac{5}{2}(2)RT$
$U_\text{total} = 3RT + 5RT$
$U_\text{total} = 8RT$
The correct answer is (C) 8 RT.