32
A cube of side 4 cm is cut into 1 cm cubes, so the number of smaller cubes is \( 4^3 = 64 \).
To find cubes with exactly one face painted, consider the cubes on each face of the large cube. Each face of the cube has \( 4 \times 4 = 16 \) smaller cubes, but the edge and corner cubes are share(d)
Cubes with exactly one face painted are those on the surface, excluding edges and corners. For each face:
Inner cubes = \( (4 - 2) \times (4 - 2) = 2 \times 2 = 4 \).
There are 6 faces, so total cubes with one face painted = \( 6 \times 4 = 24 \).
Thus, the answer is 24.