Step 1: Initial charge on the first capacitor.
The initial charge \( Q_1 \) on the first capacitor is given by:
\[
Q_1 = C_1 V = 10 \, \mu\text{F} \times 6 \, \text{V} = 60 \, \mu\text{C}.
\]
Step 2: When the second capacitor is connected.
When the second capacitor \( C_2 = 20 \, \mu\text{F} \) is connected in parallel, the total capacitance becomes:
\[
C_{\text{total}} = C_1 + C_2 = 10 \, \mu\text{F} + 20 \, \mu\text{F} = 30 \, \mu\text{F}.
\]
Step 3: Final charge distribution.
The charge is distributed across the two capacitors. The charge on the second capacitor is:
\[
Q_2 = \frac{C_2}{C_{\text{total}}} \times Q_1 = \frac{20}{30} \times 60 = 40 \, \mu\text{C}.
\]
Final Answer:
\[
\boxed{40 \, \mu\text{C}}.
\]