To find the final temperature, we use the principle of conservation of energy, which states that the heat lost by the hotter sample is equal to the heat gained by the colder sample:
\[
m_1 c \Delta T_1 = m_2 c \Delta T_2
\]
Where:
- \( m_1 = 1.0 \, \text{kg} = 1000 \, \text{g} \) (mass of the hot sample),
- \( m_2 = 2.0 \, \text{kg} = 2000 \, \text{g} \) (mass of the cold sample),
- \( c = 4.18 \, \text{J/g}^\circ \text{C} \) (specific heat capacity of water),
- \( \Delta T_1 = T_{\text{final}} - 80 \) (change in temperature of the hot sample),
- \( \Delta T_2 = T_{\text{final}} - 20 \) (change in temperature of the cold sample).
Setting up the energy balance:
\[
1000 \times 4.18 \times (T_{\text{final}} - 80) = 2000 \times 4.18 \times (T_{\text{final}} - 20)
\]
Canceling the \( 4.18 \) term from both sides:
\[
1000 \times (T_{\text{final}} - 80) = 2000 \times (T_{\text{final}} - 20)
\]
Expanding both sides:
\[
1000 T_{\text{final}} - 80000 = 2000 T_{\text{final}} - 40000
\]
Solving for \( T_{\text{final}} \):
\[
1000 T_{\text{final}} - 2000 T_{\text{final}} = -40000 + 80000
\]
\[
-1000 T_{\text{final}} = 40000
\]
\[
T_{\text{final}} = 40^\circ C
\]
Thus, the final equilibrium temperature is \( 45^\circ C \).