Question:

$56.0 \,L$ of nitrogen gas is mixed with excess of hydrogen gas and it is found that $20\, L$ of ammonia gas is produced The volume of unused nitrogen gas is found to be _______ $L$

Updated On: Dec 30, 2024
Hide Solution
collegedunia
Verified By Collegedunia

Correct Answer: 46

Approach Solution - 1

The correct answer is 46
 
To solve this problem, we can use the balanced chemical equation for the reaction between nitrogen gas (N2) and hydrogen gas (H2) to form ammonia gas (NH3):
N2 + 3H2 → 2NH3
According to the stoichiometry of the balanced equation, 1 mole of N2 reacts with 3 moles of H2 to produce 2 moles of NH3.
Given: Volume of nitrogen gas (N2) = 56.0 L Volume of ammonia gas (NH3) produced = 20 L
Using the ideal gas law, we can relate the volume of a gas to the number of moles of that gas:
n = PV / RT
where: n is the number of moles of the gas P is the pressure of the gas V is the volume of the gas R is the gas constant (0.0821 L·atm/(mol·K)) T is the temperature in Kelvin
Let's calculate the number of moles of nitrogen gas (N2):
n(N2) = (P(N2) * V(N2)) / (R * T)
Since the pressure, volume, and temperature are not specified, we can assume they are constant throughout the reaction. Therefore, we can write:
n(N2) = n(NH3) * (1 mole N2 / 2 moles NH3)
n(N2) = (20 L * 1 mole N2) / (2 moles NH3)
n(N2) = 10 L
Now, let's calculate the volume of unused nitrogen gas (N2):
V(unused N2) = V(N2 initial) - V(N2 used)
V(unused N2) = 56.0 L - 10 L
V(unused N2) = 46.0 L
Therefore, the volume of unused nitrogen gas is 46.0 L.


 

Was this answer helpful?
9
9
Hide Solution
collegedunia
Verified By Collegedunia

Approach Solution -2

The correct answer is 46
\(N_2(g)+3H_2(g)→2NH_3(g)\)
Since H2 is in excess and 20 L of ammonia gas is produced.
Hence, 2 moles NH3 ≡ 1 mole N2 (v∝n)
20 L NH3≡10 L N2
Volume of N2 left =56–10
=46 L

Was this answer helpful?
6
2

Concepts Used:

Dihydrogen

Dihydrogen is the homonuclear diatomic molecule built from two hydrogen atoms. This molecule characterizes a covalent bond between two hydrogen atoms, satisfying each of their required pair configurations.

Structure of Dihydrogen:

The dihydrogen molecule characterizes a single covalent bond between the two hydrogen atoms that comprise it. This molecule has a linear shape and is nonionic in nature. Each hydrogen atom comes up with one electron towards the covalent bond.

Properties of Dihydrogen:

  • At Standard Temperature and Pressure (STP), dihydrogen exists in the gaseous state.
  • The melting point of H2 is 13.99 Kelvin. Transforming this value to the celsius scale, the melting point of dihydrogen can be expressed as -259.16 degrees celsius.
  • The boiling point correlated with dihydrogen corresponds to 20.271 on the Kelvins scale. Transforming this value into the celsius scale, the boiling point of H2 can be represented as -252.879 degrees celsius.
  • The latent heat of fusion associated with the H2 molecule correlates to 0.117 kilojoules per mole.
  • The latent heat of vaporization (also known as the enthalpy of vaporization) of dihydrogen is equivalent to 0.904 kilojoules per mole.