- Heat Evolved by the Reaction:
- The reaction 2Hg(g)+O2(g)→2HgO(s) releases heat, and it's found to be 296kJ. This is determined from the rise in temperature in the calorimeter, which has a heat capacity of 20 kJ K−1, and the temperature rose by 14.8K.
- Calculation of ΔH∘:
- Using the relation ΔH∘=ΔU∘+Δ(ngRT), we find:
ΔH∘=−296kJ−(3×8.3J K−1mol−1×298K×10−3)≈−303.42kJ
- Calculation of ΔH∘ for HgO(s):
- By using Hess's Law, we can relate the enthalpy change for the reaction to the enthalpies of formation for the substances involved:
ΔH∘(HgO(s))=ΔH∘(HgO(s))−ΔH∘(Hg(g))−2×ΔH∘(Hg(s))
- Substituting the values gives:
ΔH∘(HgO(s))=−303.42+122.64−180.78=−303.42+90.39kJ mol−1
Thus, the absolute value of the enthalpy of formation for solid mercury oxide HgO(s)) is 90.39 kJ mol−1.