Question:

100 mL of Na\(_3\)PO\(_4\) solution contains 3.45 g of sodium. The molarity of the solution is __________ \(\times\)10\(^{-2}\) mol L\(^{-1}\). (Nearest integer)
[Atomic Masses - Na: 23.0 u, O: 16.0 u, P: 31.0 u]

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In problems involving stoichiometry of solutions, always use the mole concept. Find the moles of the substance for which data is given (here, sodium) and then use the stoichiometric ratio from the chemical formula to find the moles of the required substance (here, Na\(_3\)PO\(_4\)). Finally, apply the definition of concentration (molarity, molality, etc.).
Updated On: Dec 30, 2025
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Correct Answer: 50

Solution and Explanation

Step 1: Understanding the Question
We are given the volume of a sodium phosphate (Na\(_3\)PO\(_4\)) solution and the mass of sodium ions it contains. We need to calculate the molarity of the Na\(_3\)PO\(_4\) solution.
Step 2: Key Formula or Approach
Molarity (M) is defined as the number of moles of solute per liter of solution.
\[ \text{Molarity} = \frac{\text{Moles of solute}}{\text{Volume of solution in L}} \] We can find the moles of Na\(_3\)PO\(_4\) from the given mass of sodium.
Step 3: Detailed Calculation
Calculate moles of Sodium (Na):
Given mass of Na = 3.45 g
Atomic mass of Na = 23.0 g/mol
\[ \text{Moles of Na} = \frac{\text{Mass}}{\text{Atomic mass}} = \frac{3.45 \text{ g}}{23.0 \text{ g/mol}} = 0.15 \text{ mol} \] Calculate moles of Sodium Phosphate (Na\(_3\)PO\(_4\)):
From the chemical formula Na\(_3\)PO\(_4\), we can see that 1 mole of Na\(_3\)PO\(_4\) contains 3 moles of Na atoms.
\[ \text{Moles of Na}_3\text{PO}_4 = \frac{\text{Moles of Na}}{3} = \frac{0.15 \text{ mol}}{3} = 0.05 \text{ mol} \] Calculate Molarity:
Moles of solute (Na\(_3\)PO\(_4\)) = 0.05 mol
Volume of solution = 100 mL = 0.100 L
\[ \text{Molarity} = \frac{0.05 \text{ mol}}{0.100 \text{ L}} = 0.5 \text{ mol L}^{-1} \] Express the answer in the required format:
The question asks for the answer in the format of _________ \(\times\) 10\(^{-2}\) mol L\(^{-1}\).
\[ 0.5 = 50 \times 10^{-2} \] Step 4: Final Answer
The molarity is 0.5 M, which is equal to 50 \(\times\) 10\(^{-2}\) M. The nearest integer value is 50.
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