Question:

1, 3-butadiene has:

Updated On: Aug 7, 2023
  • sp and sp2 hybridised C-atoms

  • sp, sp2 and sp3 hybridised C-atoms

  • only sp2 hybridised C-atoms

  • only sp hybridised C-atoms

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The Correct Option is C

Approach Solution - 1

H2C == CH - - HC == CH2

1, 3 butadiene

In this compound, each carbon is sp2 hybridised, (as each carbon has one double bond).

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Approach Solution -2

The correct option is (C): 1,3− butadiene has only sp2 hybridized C− atoms 

1,3-Butadiene is a chemical compound with the molecular formula C4H6

  • It is an unsaturated hydrocarbon that contains four carbon atoms and six hydrogen atoms arranged in a linear fashion. 
  • The carbon atoms in 1,3-butadiene are sp2 hybridized, meaning that each carbon atom has three sp2 orbitals and one p orbital in its valence shell.

CH2 = CH - CH= CH2

sp2       sp2       sp2    sp2

This hybridization of the carbon atoms results in a planar arrangement of the molecule, which makes it highly reactive. 

  • The double bonds between the carbon atoms are electron-rich and are vulnerable to reactions with other chemicals, including addition and substitution reactions
  • These double bonds give 1,3-butadiene its unsaturated character, making it a common starting material for the production of various polymers, such as synthetic rubber.

Hence, 1,3-butadiene is a linear unsaturated hydrocarbon with only sp2 hybridized carbon atoms, which makes it highly reactive and useful as a starting material in the synthesis of various polymers.

Therefore, option C is the correct answer.

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Concepts Used:

Alkenes

Alkenes

In organic chemistry, an alkene is a hydrocarbon containing a carbon-carbon double bond.[1]

Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.

Read More: Ozonolysis

IUPAC Nomenclature of Alkenes

  1. An alkene or cycloalkene is indicated by the suffix (ending) ene.
  2. For the root name, the longest chain must include both carbon atoms of the double bond.
  3. The root chain must be numbered beginning at the end closest to a double bond carbon atom. If the double bond is in the chain's centre, the nearest substituent rule is used to determine where the numbering begins.
  4. If the compound contains more than one double bond, it is named with a diene, triene, or equivalent prefix indicating the number of double bonds, and each double bond is assigned a locator number.

Read More: Unsaturated Hydrocarbon