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Chemistry
List of top Chemistry Questions
Purine bases present in
$DNA$
are adenine and guanine. The base thymine is present in
$RNA$
while base uracil is present in
$DNA$
.
Chemistry
Biomolecules
$pK_a$
value of phenol is
$10.0$
while that of ethanol is
$15.9$
Ethanol is stronger acid than phenol.
Chemistry
Alcohols, Phenols and Ethers
$ PHBV$
is a biodegradable polymer.
$ PHBV$
is an aliphatic polyester.
Chemistry
Polymers
Oxidation state of oxygen in
$OF_{2}$
and
$Na_{2}O$
is
$+2$
and
$-2$
respectively. Oxygen is an electronegative element.
Chemistry
Classification of elements and periodicity in properties
$O_{2}$
molecule is diamagnetic while
$C_{2}$
molecule is paramagnetic in nature. Bond order of
$O_ 2$
molecule is
$1.5$
and that of
$C_2$
molecule is
$2.5$
.
Chemistry
Chemical bonding and molecular structure
$Na_{2}O$
is basic oxide whereas
$Cl_{2}O_{7}$
is acidic oxide. Elements on extreme left form basic oxides whereas elements on extreme right form acidic oxides.
Chemistry
Classification of elements and periodicity in properties
Lyophilic colloids have a unique property of protecting lyophobic colloids. Lyophilic colloids are extensively solvated.
Chemistry
Surface Chemistry
Lithium salts are mostly hydrated. The hydration enthalpies of alkali metal ions decrease with increase in ionic sizes.
Chemistry
GROUP 1 ELEMENTS
$K_4[Fe(CN)_6]$
is diamagnetic and
$[Fe(H_2O)_6 ]Cl_3$
is paramagnetic. Hybridisation of central metal m
$K_4[Fe(CN)_6] is \,sp^3d^2,$
while in
$[Fe(H_2O)_6]Cl_3\, is\, d^2\, sp^3$
Chemistry
coordination compounds
Isocyanide test can be used to distinguish between secondary and tertiary amines. Tertiary amines on heating with chloroform and ale.
$KOH$
form foul smelling substances.
Chemistry
Amines
In the series
$Sc$
to
$Zn$
, the enthalpy of atomisation of zinc is the lowest. Zinc has greater number of unpaired electrons.
Chemistry
d -and f -Block Elements
In vapour state sulphur is paramagnetic in nature. In vapour state sulphur exists as
$S_2$
molecule.
Chemistry
p -Block Elements
In the metallury of aluminium, purified
$Al_2O_3$
is mixed with
$Na_3AlF_6$
or
$CaF_2$
.
$Na_3AlF_6$
or
$CaF_2$
lowers the melting point of mixture and increases its conductivity.
Chemistry
General Principles and Processes of Isolation of Elements
In the presence of alkaline
$KMnO_{4} 4-$
methylacetophenone is oxidised to benzoic acid. Keto group is oxidised to
$??OOH$
group.
Chemistry
Aldehydes, Ketones and Carboxylic Acids
In the reaction,
$2Cu_{2}O_{\left(s\right)}+Cu_{2}S_{\left(s\right)} \rightarrow 6 Cu_{\left(s\right)}+SO_{2\left(g\right)}$
copper acts as a reductant and sulphur acts as an oxidant. The given reaction is not a redox reaction.
Chemistry
Redox reactions
In Rutherford??
$\alpha$
-particle scattering experiment, most of the
$\alpha$
-particles were deflected by nearly
$180^{\circ}$
. The positive charge of the atom is spread throughout the atom that repelled and deflected the positively charged
$\alpha$
-particles.
Chemistry
Structure of atom
In
$NH_3, N$
is
$sp^3$
hybridised but bond angle is
$107^{\circ}$
. Shape of
$NH_{3}$
molecule is trigonal pyramidal.
Chemistry
Chemical bonding and molecular structure
In hydrogen and hydrogen like species, orbital energy depends only on the quantum number
$n$
whereas in multi-electron atoms it depends on quantum numbers
$n$
and
$I$
. The principal quantum number determines the size and the energy of the orbital.
Chemistry
Structure of atom
In crystalline solids, the value of resistance is different in different directions. Crystalline solids are isotropic in nature.
Chemistry
The solid state
Hydrolysis of ester is an example of auto catalytic reaction. A catalyst speeds up the process without participating in the mechanism.
Chemistry
Surface Chemistry
Hofmann degradation of benzamide gives aniline. Hofmann bromamide degradation reaction can be used for descending amine series.
Chemistry
Amines
$HNO_{2}$
can act both as a reducing agent and an oxidising agent. In
$HNO_{2},$
oxidation state of nitrogen is
$+3 $
which can change from
$-3$
to
$+5$
.
Chemistry
Redox reactions
Haloalkanes react with
$KCN$
to form alkyl cyanides as main product while with
$AgCN$
form isocyanide as the main product.
$KCN$
and
$AgCN$
, both are ionic compounds.
Chemistry
Haloalkanes and Haloarenes
Geometrical isomerism is also called cis-trans isomerism. Tetrahedral complexes show geometrical isomerism.
Chemistry
coordination compounds
Glucose gets oxidised to gluconic acid on reaction with mild oxidising agent like bromine water. Glucose contains a keto group.
Chemistry
Biomolecules
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