Write the significance of a plus and a minus sign shown in representing the orbitals.
Solution and Explanation
Molecular orbitals are represented by wave functions. A plus sign in an orbital indicates a positive wave function while a minus sign in an orbital represents a negative wave function.
Top Questions on Molecular Orbital Theory
- In the following, the number of paramagnetic molecules are: O\(_2\), N\(_2\), F\(_2\), B\(_2\), Cl\(_2\).
- JEE Main - 2025
- Chemistry
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Which of the following statement is true with respect to H\(_2\)O, NH\(_3\) and CH\(_4\)?
(A) The central atoms of all the molecules are sp\(^3\) hybridized.
(B) The H–O–H, H–N–H and H–C–H angles in the above molecules are 104.5°, 107.5° and 109.5° respectively.
(C) The increasing order of dipole moment is CH\(_4\)<NH\(_3\)<H\(_2\)O.
(D) Both H\(_2\)O and NH\(_3\) are Lewis acids and CH\(_4\) is a Lewis base.
(E) A solution of NH\(_3\) in H\(_2\)O is basic. In this solution NH\(_3\) and H\(_2\)O act as Lowry-Bronsted acid and base respectively.
- JEE Main - 2025
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Which of the following linear combinations of atomic orbitals will lead to the formation of molecular orbitals in homonuclear diatomic molecules (internuclear axis in z-direction)?
(1) \( 2p_z \) and \( 2p_x \)
(2) \( 2s \) and \( 2p_x \)
(3) \( 3d_{xy} \) and \( 3d_{x^2-y^2} \)
(4) \( 2s \) and \( 2p_z \)
(5) \( 2p_z \) and \( 3d_{x^2-y^2} \)
- JEE Main - 2025
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- Arrange the following in increasing order of bond order: (A) He\(_2^+\)
(B) O\(_2^-\)
(C) HF
(D) NO\(^-\)- CUET (PG) - 2025
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- The sum of the bond orders of O$_2^+$, O$_2^-$, O$_2$, O$_2^{2-$, and the sum of the unpaired electrons in them respectively are
- AP EAPCET - 2025
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Questions Asked in CBSE Class XI exam
- Identify the substance oxidised, reduced, oxidising agent and reducing agent for each of the following reactions:
- \(2AgBr (s) + C_6H_6O_2(aq) \rightarrow 2Ag(s) + 2HBr (aq) + C_6H_4O_2(aq)\)
- \(HCHO(l) + 2[Ag (NH_3)_2] ^+ (aq) + 3OH^ - (aq) \rightarrow 2Ag(s) + HCOO ^- (aq) + 4NH_3(aq) + 2H_2O(l)\)
- \(HCHO (l) + 2Cu^{ 2+}(aq) + 5 OH^ - (aq) \rightarrow Cu_2O(s) + HCOO ^- (aq) + 3H_2O(l)\)
- \(N_2H_4(l) + 2H_2O_2(l) \rightarrow N_2(g) + 4H_2O(l)\)
- \(Pb(s) + PbO_2(s) + 2H_2SO_4(aq) \rightarrow 2PbSO_4(s) + 2H_2O(l)\)
- CBSE Class XI
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Figure 8.9 shows the strain-stress curve for a given material. What are (a) Young’s modulus and (b) approximate yield strength for this material?
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- Stress-strain curve
- Three reasons why the author’s grandmother was disturbed when he started going to the city school.
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- The Portrait of a lady
Two identical ball bearings in contact with each other and resting on a frictionless table are hit head-on by another ball bearing of the same mass moving initially with a speed V. If the collision is elastic, which of the following (Fig. 5.14) is a possible result after collision ?
- CBSE Class XI
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- Why is it necessary to use acetic acid and not sulphuric acid for acidification of sodium extract for testing sulphur by lead acetate test?
- CBSE Class XI
- Organic Chemistry
Concepts Used:
Chemical Bonding and Molecular Structure
Such a group of atoms is called a molecule. Obviously, there must be some force that holds these constituent atoms together in the molecules. The attractive force which holds various constituents (atoms, ions, etc.) together in different chemical species is called a chemical bond.
Types of Chemical Bonds:
There are 4 types of chemical bonds which are formed by atoms or molecules to yield compounds.
- Ionic Bonds - Ionic bonding is a type of chemical bonding which involves a transfer of electrons from one atom or molecule to another.
- Covalent Bonds - Compounds that contain carbon commonly exhibit this type of chemical bonding.
- Hydrogen Bonds - It is a type of polar covalent bonding between oxygen and hydrogen wherein the hydrogen develops a partial positive charge
- Polar Bonds - In Polar Covalent chemical bonding, electrons are shared unequally since the more electronegative atom pulls the electron pair closer to itself and away from the less electronegative atom.
Factors Affecting Bond Enthalpy in Chemical Bonding:
- Size of the Atom
- Multiplicity of Bonds
- Number of Lone Pair of Electrons Present
- Bond Angle