Write the important conditions required for the linear combination of atomic orbitals to form molecular orbitals.
Solution and Explanation
The given conditions should be satisfied by atomic orbitals to form molecular orbitals:
(a) The combining atomic orbitals must have the same or nearly the same energy. This means that in a homonuclear molecule, the \(1s-atomic\) orbital of an atom can combine with the \(1s-atomic\) orbital of another atom, and not with the \(2s-orbital\).
(b) The combining atomic orbitals must have proper orientations to ensure that the overlap is maximum.
(c) The extent of overlapping should be large.
Top Questions on Molecular Orbital Theory
Which of the following statement is true with respect to H\(_2\)O, NH\(_3\) and CH\(_4\)?
(A) The central atoms of all the molecules are sp\(^3\) hybridized.
(B) The H–O–H, H–N–H and H–C–H angles in the above molecules are 104.5°, 107.5° and 109.5° respectively.
(C) The increasing order of dipole moment is CH\(_4\)<NH\(_3\)<H\(_2\)O.
(D) Both H\(_2\)O and NH\(_3\) are Lewis acids and CH\(_4\) is a Lewis base.
(E) A solution of NH\(_3\) in H\(_2\)O is basic. In this solution NH\(_3\) and H\(_2\)O act as Lowry-Bronsted acid and base respectively.
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Questions Asked in CBSE Class XI exam
Give reasons for the following.
(i) King Tut’s body has been subjected to repeated scrutiny.
(ii) Howard Carter’s investigation was resented.
(iii) Carter had to chisel away the solidified resins to raise the king’s remains.
(iv) Tut’s body was buried along with gilded treasures.
(v) The boy king changed his name from Tutankhaten to Tutankhamun.- CBSE Class XI
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Find the mean deviation about the median for the data
xi 15 21 27 30 35 fi 3 5 6 7 8 - CBSE Class XI
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- The Cartesian product A x A has 9 elements among which are found (-1, 0) and (0, 1). Find the set A and the remaining elements of A x A.
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- ‘Have you come back?’ said the woman. ‘I thought that no one had come back.’ Does this statement give some clue about the story? If yes, what is it?
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- In a class of 60 students, 30 opted for NCC, 32 opted for NSS and 24 opted for both NCC and NSS. If one of these students is selected at random, find the probability that
(i)The student opted for NCC or NSS.
(ii)The student has opted neither NCC nor NSS.
(iii)The student has opted NSS but not NCC- CBSE Class XI
- Axiomatic Approach to Probability
Concepts Used:
Chemical Bonding and Molecular Structure
Such a group of atoms is called a molecule. Obviously, there must be some force that holds these constituent atoms together in the molecules. The attractive force which holds various constituents (atoms, ions, etc.) together in different chemical species is called a chemical bond.
Types of Chemical Bonds:
There are 4 types of chemical bonds which are formed by atoms or molecules to yield compounds.
- Ionic Bonds - Ionic bonding is a type of chemical bonding which involves a transfer of electrons from one atom or molecule to another.
- Covalent Bonds - Compounds that contain carbon commonly exhibit this type of chemical bonding.
- Hydrogen Bonds - It is a type of polar covalent bonding between oxygen and hydrogen wherein the hydrogen develops a partial positive charge
- Polar Bonds - In Polar Covalent chemical bonding, electrons are shared unequally since the more electronegative atom pulls the electron pair closer to itself and away from the less electronegative atom.
Factors Affecting Bond Enthalpy in Chemical Bonding:
- Size of the Atom
- Multiplicity of Bonds
- Number of Lone Pair of Electrons Present
- Bond Angle