Step 1: General reaction.
Nucleophilic substitution occurs when a nucleophile replaces a leaving group (like Br\(^-\)) in ethyl bromide (C\(_2\)H\(_5\)Br).
Step 2: Example reaction with aqueous KOH.
\[
C_2H_5Br + OH^- \;\longrightarrow\; C_2H_5OH + Br^-
\]
Here, the hydroxide ion acts as the nucleophile, replacing bromine, and producing ethanol.
Final Answer:
\[
\boxed{C_2H_5Br + KOH(aq) \;\rightarrow\; C_2H_5OH + KBr}
\]