Which type of tannins is related to the flavonoid pigment having polymeric flavan-3-ol structure?
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Condensed tannins are non-hydrolysable and yield anthocyanidins upon acid hydrolysis, reflecting their polymeric flavan-3-ol nature. Hydrolysable tannins, on the other hand, are esters of gallic acid or ellagic acid with a core polyol.
Condensed tannins, also known as proanthocyanidins, are oligomeric or polymeric flavonoids composed of flavan-3-ol units. These units, such as catechin and epicatechin, polymerize to form complex structures. Flavonoid pigments, including anthocyanins and flavanols, share a common biosynthetic pathway with these tannins, and condensed tannins are directly related to the polymeric forms of flavan-3-ols.