Step 1: Antioxidant.
- Antioxidants prevent degradation by oxidation.
- Aromatic amines like Phenyl $\beta$-naphthyl amine are classic antioxidants.
\(\Rightarrow P-4\).
Step 2: Flame retardant.
- Organophosphates (like tricresyl phosphate) are flame retardants.
\(\Rightarrow Q-3\).
Step 3: Plasticizer.
- Di(2-ethylhexyl) phthalate (DEHP) is one of the most common plasticizers used in PVC.
\(\Rightarrow R-2\).
Step 4: Colorant.
- Phthalocyanines are well-known colorants (blue/green pigments).
\(\Rightarrow S-1\).
Final Mapping:
\[
P-4,\; Q-3,\; R-2,\; S-1
\]
Final Answer:
\[
\boxed{\text{(A) P-4; Q-3; R-2; S-1}}
\]