We are given:
- Heat of polymerization = \( 25 \, {Kcal/mol} \)
- Mass of polyethylene = \( 5.6 \, {kg} = 5600 \, {g} \)
- Molar mass of polyethylene (monomer unit ethylene) = \( 28 \, {g/mol} \)
To find the total number of moles of ethylene polymerized:
\[
{Moles of ethylene} = \frac{5600 \, {g}}{28 \, {g/mol}} = 200 \, {mol}
\]
Now calculate the total heat released:
\[
{Heat} = 200 \, {mol} \times 25 \, {Kcal/mol} = 5000 \, {Kcal}
\]