The octet rule states that atoms in molecules tend to have eight electrons in their valence shell, like the noble gases. However, some molecules do not follow this rule.
SF\(_6\): Sulfur has more than eight electrons in its valence shell, as it is able to accommodate more than eight electrons due to the availability of d-orbitals.
AlCl\(_3\): Aluminum in AlCl\(_3\) only has six electrons in its valence shell, which is an example of an incomplete octet, meaning it does not satisfy the octet rule.
CH\(_4\): Carbon in CH\(_4\) follows the octet rule as it shares four electrons with four hydrogen atoms, completing its octet.
PF\(_5\): Phosphorus in PF\(_5\) has ten electrons in its valence shell, which is allowed as phosphorus can expand its octet.
H\(_2\)O: Oxygen in H\(_2\)O has eight electrons in its valence shell, fulfilling the octet rule.
Thus, the molecule AlCl\(_3\) contains an incomplete octet of the central atom.
The correct option is (B) : \(AlCI_3\)
Match the LIST-I with LIST-II:
Choose the correct answer from the options given below :
The number of molecules/ions that show linear geometry among the following is _____. SO₂, BeCl₂, CO₂, N₃⁻, NO₂, F₂O, XeF₂, NO₂⁺, I₃⁻, O₃
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: