Question:

Which one of the following is an example for homogeneous catalysis?

Updated On: Aug 1, 2022
  • Manufacture of ammonia by Haber's process
  • Manufacture of sulphuric acid by contact process
  • Hydrogenation of oil
  • Hydrolysis of sucrose in presence of dilute hydrochloric acid
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The Correct Option is D

Solution and Explanation

In homogeneous catalysis, reactants and catalyst are in the same phase. (a) $SO _{2}(g)+ O _{2}(g) \stackrel{ Pt (s)}{\rightleftharpoons} SO _{3}(g)$ (Contact process) It is an example of heterogeneous catalysis. (b) $N _{2}(g)+ H _{2}(g) \stackrel{ Fe (s)}{\rightleftharpoons} 2 NH _{3}(g)$ (Haber's process) It is an example of heterogeneous catalysis. (c) $C _{12} H _{22} O _{11}(a q)+ H _{2} O (a q) \stackrel{ HCl (a q)}{\rightleftharpoons} C _{6} H _{12} O _{6}$ $+ C _{6} H _{12} O _{6}$ It is an example of homogeneous catalysis. $ {Oil (l) +H_2(g) ->[{(Hardening)}][{Pt(s)}] fat}$ Thus, it is also an example of heterogeneous catalysis.
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Concepts Used:

Surface Chemistry

The study of the chemical phenomena that occur at the interface of two surfaces which can be solid-liquid, solid-gas, solid-vacuum, liquid-gas, etc. 

Read Also: Surface Chemistry

Applications of surface chemistry are:

Adsorption:

The process of attraction and aggregation of the molecules of a substance on the surface of a solid is known as adsorption. For Example, N2 adsorbs on the surface of activated charcoal

Two types of adsorption are:-

  • Chemisorption: It is also known as Chemical Adsorption.
  • Physisorption: It is also known as Physical Adsorption.

Corrosion:

The process through which the refined metals convert themselves into more stable compounds is known as corrosion.

Crystallisation:

The type of technique used in order to purify the substances to separate Solids from liquids is known as crystallisation.

Heterogeneous Catalysis:

The process wherein a catalyst is used in order to increase the rate of a chemical reaction is known as catalysis. The catalyst does not undergo any transformation and can be recovered in a chemically unchanged state. 

There are two types of catalysis:-

  • When the catalyst involved and the reacting substances are same states of matter or in the same phase, it is known as Homogeneous Catalysis.
  • When the catalyst involved and the reacting substances are in different states of matter or different phases, it is known as Heterogeneous Catalysis.