$C _{4} H _{10} O _{4}$ is $C _{n} H _{2 n+2}$ type compound, ie with unsaturation factor $0, C _{4} H _{8} O _{4}$ and $C _{4} H _{7} ClO _{4}$ are $C _{n} H _{2 n}$ (unsaturated) type compound, ie, have unsaturation factor 1 while $C _{4} H _{9} O _{4}$ is $C _{n} H _{2 n+1}$ type compound with unsaturation factor 0.5. Hence, $C _{4} H _{9} O _{4}$ does not represent an organic compound.
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Top Questions on Organic Chemistry - Some Basic Principles and Techniques