Correct Answer:
Option 1: Equilibrium constant may increase or decrease, but rate constant always increases with temperature.
Explanation:
Rate Constant (k):
The rate constant (k) is related to temperature by the Arrhenius equation: k = A * e(-Ea/RT).
As temperature (T) increases, the rate constant (k) always increases.
Equilibrium Constant (K):
The equilibrium constant (K) is related to the rate constants of the forward and reverse reactions: K = kf / kr.
The temperature dependence of K is given by the van 't Hoff equation: d(ln K)/dT = ΔH°/RT2.
Therefore, the equilibrium constant can either increase or decrease, depending on the reaction.
\( \text{M} \xrightarrow{\text{CH}_3\text{MgBr}} \text{N} + \text{CH}_4 \uparrow \xrightarrow{\text{H}^+} \text{CH}_3\text{COCH}_2\text{COCH}_3 \)
Identify the ion having 4f\(^6\) electronic configuration.