Let’s examine the correctness of each statement:
- (1) Correct: Catalytic converters reduce emissions including nitrogen oxides.
- (2) Incorrect: Photochemical smog is primarily a mixture of smoke, fog, and hydrocarbons with \(\mathrm{NO_x}\) and ozone — not \(\mathrm{SO_2}\).
- (3) Correct: Chlorofluorocarbons are known to deplete the ozone layer.
- (4) Correct: Acid rain can cause corrosion of water pipes, leading to leaching of toxic metals.
Therefore, Option (2) is incorrect.