Question:

Which of the following solutions can form a minimum boiling azeotrope?

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Minimum boiling azeotropes are commonly formed by mixtures of water and alcohols, such as ethanol. These mixtures have a constant boiling point and cannot be separated by distillation.
Updated On: Apr 12, 2025
  • \( \text{C}_2\text{H}_5\text{OH} + \text{H}_2\text{O} \)
  • \( \text{n-heptane} + \text{n-hexane} \)
  • \( \text{CH}_3\text{COOH} + \text{C}_5\text{H}_5\text{N} \)
  • \( \text{C}_2\text{H}_5\text{Br} + \text{C}_2\text{H}_5\text{I} \)
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The Correct Option is A

Solution and Explanation

Azeotropes are mixtures of two liquids that boil at a constant temperature and cannot be separated by simple distillation.
A minimum boiling azeotrope is formed when the mixture exhibits a boiling point lower than that of either pure component. Examine the components of the given mixtures:
Ethanol (C\(_2\)H\(_5\)OH) and Water (H\(_2\)O) form a minimum boiling azeotrope at about 78.2°C.
This azeotrope cannot be separated by distillation, making it the correct option. The other mixtures like n-heptane and n-hexane form ideal solutions and do not form minimum boiling azeotropes. Thus, the correct answer is (1).
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