Question:

Which of the following reactions of KMnO$_4$ occurs in acidic medium?

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KMnO$_4$ in acidic medium is a strong oxidizing agent and is commonly used to oxidize sulfides to elemental sulfur and other oxidation reactions.
Updated On: Mar 24, 2025
  • Oxidation of thiosulphate to sulphate
  • Precipitation of sulphur from H$_2$S
  • Oxidation of iodide to iodate
  • Oxidation of manganous salt to MnO$_2$
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The Correct Option is B

Solution and Explanation

Potassium Permanganate Reaction in Acidic Medium

In acidic medium, \( \text{KMnO}_4 \) acts as an oxidizing agent. The reaction of \( \text{KMnO}_4 \) with \( \text{H}_2\text{S} \) leads to the precipitation of sulphur. This reaction occurs in acidic medium, where \( \text{KMnO}_4 \) oxidizes \( \text{H}_2\text{S} \) to sulphur. The other reactions do not occur in acidic medium or are not typical reactions for \( \text{KMnO}_4 \).

Conclusion:

Therefore, the correct answer is Precipitation of sulphur from \( \text{H}_2\text{S} \).

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