Step 1: First, recall the dimensional formulas for each of the physical quantities:
Step 2: Now, calculate the dimensions of each given option.
For option \( \frac{hc}{m} \):
\[ \left[ \frac{hc}{m} \right] = \frac{[ML^2T^{-1}][LT^{-1}]}{[M]} = [L^2T^{-2}] \]
which does not correspond to the dimension of length.
For option \( \frac{h}{mc^2} \):
\[ \left[ \frac{h}{mc^2} \right] = \frac{[ML^2T^{-1}]}{[M][L^2T^{-2}]} = [T] \]
which corresponds to the dimension of time, not length.
For option \( \frac{h^2}{m^2c^2} \):
\[ \left[ \frac{h^2}{m^2c^2} \right] = \frac{[M^2L^4T^{-2}]}{[M^2][L^2T^{-2}]} = [L^2] \]
which corresponds to the dimension of area, not length.
For option \( \frac{h}{mc} \):
\[ \left[ \frac{h}{mc} \right] = \frac{[ML^2T^{-1}]}{[M][LT^{-1}]} = [L] \]
which corresponds to the dimension of length.
Dimensional Analysis to Find Quantity with Dimension of Length
We are asked to find which of the following quantities has the dimension of length [L], where h is Planck's constant, m is the mass of the electron, and c is the velocity of light.
The dimensions of the fundamental quantities are given as:
Planck's constant (h): $[h] = [ML^2T^{-1}]$
Velocity of light (c): $[c] = [LT^{-1}]$
Mass of electron (m): $[m] = [M]$
Checking the dimensions of each option:
(A) $\frac{hc}{m}$
Dimensions: $\frac{[ML^2T^{-1}] [LT^{-1}]}{[M]} = \frac{ML^3T^{-2}}{M} = [L^3T^{-2}]$
This does not have the dimension of length.
(B) $\frac{h}{mc^2}$
Dimensions: $\frac{[ML^2T^{-1}]}{[M] [LT^{-1}]^2} = \frac{ML^2T^{-1}}{M L^2T^{-2}} = [T^{1}]$
This has the dimension of time.
(C) $\frac{h^2}{mc^2}$
Dimensions: $\frac{[ML^2T^{-1}]^2}{[M] [LT^{-1}]^2} = \frac{M^2L^4T^{-2}}{M L^2T^{-2}} = [ML^2]$
This does not have the dimension of length.
(D) $\frac{h}{mc}$
Dimensions: $\frac{[ML^2T^{-1}]}{[M] [LT^{-1}]} = \frac{ML^2T^{-1}}{MLT^{-1}} = [L]$
This has the dimension of length.
Using the method of proportionality:
Assume Length $[L] \propto h^x c^y m^z$
$[L^1M^0T^0] = [ML^2T^{-1}]^x [LT^{-1}]^y [M]^z$
$[L^1M^0T^0] = [M^{x+z} L^{2x+y} T^{-x-y}]$
Equating the powers:
For M: $x + z = 0 \implies z = -x$
For L: $2x + y = 1$
For T: $-x - y = 0 \implies y = -x$
Substituting $y = -x$ into $2x + y = 1$:
$2x - x = 1 \implies x = 1$
Then, $y = -1$ and $z = -1$
So, $L \propto h^1 c^{-1} m^{-1} = \frac{h}{mc}$
Final Answer: (D) $\frac{h}{mc}$
Identify the major product (G) in the following reaction