Step 1: Understand selective adsorption.
Selective adsorption refers to the phenomenon where different components of a mixture are adsorbed to different extents on a solid surface.
Step 2: Principle of chromatography.
Chromatography separates components of a mixture based on their different adsorption affinities towards the stationary phase.
Step 3: Analysis of options.
(A) Electrolytic refining: Based on electrochemical principles, not adsorption.
(B) Chromatography: Correct — separation is based on selective adsorption.
(C) Polling: Used to remove impurities from molten metals, not adsorption-based.
(D) Zone refining: Based on difference in solubility of impurities in molten metal.
Step 4: Conclusion.
Chromatography is the refining process that involves selective adsorption of components.