Question:

Which of the following oxyacid of sulphur contain both S=S and S=O bonds ?

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Thiosulphuric acid is unique among sulphur oxyacids due to the presence of both S=S and S=O bonds.
Updated On: Feb 2, 2026
  • $\mathrm{H_2S_2O_5}$
  • $\mathrm{H_2S_2O_4}$
  • $\mathrm{H_2S_2O_2}$
  • $\mathrm{H_2S_2O_3}$
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The Correct Option is D

Solution and Explanation

Step 1: Structure of oxyacids of sulphur.
Different oxyacids of sulphur show different bonding patterns involving sulphur–sulphur and sulphur–oxygen bonds.

Step 2: Analysis of thiosulphuric acid.
Thiosulphuric acid $\mathrm{(H_2S_2O_3)}$ contains one sulphur atom bonded to another sulphur atom through an S=S bond and also contains S=O bonds.

Step 3: Elimination of other options.
Other given oxyacids do not simultaneously contain both S=S and S=O bonds.

Step 4: Conclusion.
Therefore, the correct answer is $\mathrm{H_2S_2O_3$}.
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