Question

Which of the following is the correct order for ease of dehydration-

• A. I > III > II > IV
• B. IV > III > II > I
• C. IV > II > III > I
• D. III > IV > II > I

Answer 1

The Correct Option is B

The ease of dehydration can be determined by comparing the stability of intermediate carbocation.
${CH3}$ $\underset{\text{(I)}}{{CH2}}$ ${CH2\quad CH2}$$\quad\quad\quad$ ${CH3}$ $\underset{\text{(II)}}{{CH2}}$ ${CH\quad CH3}$
${CH2}$ $\underset{\text{(III)}}{{CH}}$ ${CH\quad CH3}$
(IV) intermediate carbocation is most stable due to resonance followed by (III) which is allylic carbocation. Next is (II) as it is a secondary carbocation and least stable is (I) as it is a primary carbocation. Alternatively, ease of dehydration can be determined from the stability of the product formed.