Question:

Which of the following is not isoelectronic?

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To check for isoelectronic species, sum the atomic numbers and adjust for ionic charges to get the total number of electrons.
  • CO
  • CN$^-$
  • NO$^+$
  • O$_2^{2-}$
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The Correct Option is D

Solution and Explanation

Isoelectronic species have the same number of electrons. Let's count the total electrons in each:
  • CO: C (6) + O (8) = 14 electrons
  • CN$^-$: C (6) + N (7) + 1 (from charge) = 14 electrons
  • NO$^+$: N (7) + O (8) − 1 (due to positive charge) = 14 electrons
  • O$_2^{2-}$: O (8 × 2) + 2 (from charge) = 18 electrons
So, only O$_2^{2-}$ is not isoelectronic with the others.
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